| 徐清浩,肖斌.化学通报,2020,83(7):610-614. |
| 有机锗亲核试剂的交叉偶联反应 |
| Cross-coupling Reactions of Organogermanium Nucleophiles |
| 投稿时间：2020-02-21 修订日期：2020-03-10 |
| DOI： |
| 中文关键词: 有机锗 亲核试剂 交叉偶联反应 催化 |
| 英文关键词:Organogermanium Nucleophile Cross-coupling reaction Catalysis |
| 基金项目:中科院青年创新促进会优秀会员（2015371） |
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| 中文摘要: |
| 在过渡金属催化的交叉偶联反应中，有机硅、锡化合物作为偶联亲核试剂已经广为人知，然而同族的锗元素研究却相对较少。锗亲核试剂的偶联反应最初只是简单地证明了锗作为一种“偶联元素”的可行性，但逐步发现的优异性质使得锗试剂已经受到越来越多的关注。本文从锗试剂的结构分类出发，介绍这些锗片段引入有机体系的方法及相应锗试剂的交叉偶联反应。 |
| 英文摘要: |
| Organosilane and organostannane compounds have been well-known as nucleophilic fragments in transition metal catalyzed cross-coupling reactions. However, organogermanium is less familiar to us in such case. Cross-coupling of germanium nucleophiles initially only verified germanium itself as a possible ‘cross-coupling element’, gradually showed its unique behavior, which attracted more concentration on these reagents. This article is comprised of the introducing methods and properties in cross-coupling reactions of these germanium fragments by means of their structure classification. |
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