| 章学玉,于海丰,刁全平,殷家南,息春美,吴钺.化学通报,2016,79(5):459-462. |
| FeCl3.6H2O作用的a-羰基-a-乙酰/羧基二硫缩烯酮的脱乙酰/羧基反应 |
| FeCl3.6H2O-mediated Deacetylation/Decarboxylation of a-carbonyl-a-aceto/carboxyl Ketene Dithioacetals |
| 投稿时间：2015-09-11 修订日期：2015-10-21 |
| DOI： |
| 中文关键词: 二硫缩烯酮,氯化铁,脱乙酰基反应,脱羧反应 |
| 英文关键词:ketene dithioacetals, iron (III) chloride, deacetylation, decarboxylation |
| 基金项目: |
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| 摘要点击次数: 2946 |
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| 中文摘要: |
| 探讨了价廉易得、环境友好和无毒性的FeCl3.6H2O作用的a-羰基-a-乙酰/羧基二硫缩烯酮的脱乙酰/羧基反应,高产率合成a-羰基二硫缩烯酮。该反应具有反应条件温和、环境友好和操作简单等优点。 |
| 英文摘要: |
| An inexpensive and environmentally friendly FeCl3·6H2O-mediated deacetylation/decarboxylation of ?-carbonyl-?-aceto/carboxyl ketene dithioacetals had been developed. The procedure was characterized by mild reaction condition, environmentally benign and similicity. |
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