| 陈新,黄坤林,霍俊吉,王小利.化学通报,2014,77(9):913-915. |
| 三聚氰胺和对苯二氧乙酸共晶中的三维氢键网络 |
| 3D Supramolecular Hydrogen Bonds Network in Cocrystal of Melamine and p-Phenylenedioxydiacetic Acid |
| 投稿时间：2014-01-13 修订日期：2014-02-25 |
| DOI： |
| 中文关键词: 超分子 氢键 三聚氰胺 对苯二氧乙酸 |
| 英文关键词:Supramolecular, hydrogen bond, melamine, p-phenylenedioxydiacetic acid. |
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| 中文摘要: |
| 合成了一个新的超分子聚合物[(MAH )2 (p-BDOA2-).4H2O]n(MA=三聚氰胺,p-BDOAH2=对苯二氧乙酸),通过X-射线对其结构进行了表征。在该聚合物中,三聚氰胺被质子化,相邻的三聚氰胺分子通过氢键形成一维阳离子链(MAH )n,相邻的阳离子链由p-BDOA2-阴离子连接构成波浪状的二维层,层状结构通过水分子的氢键和π-π堆积形成三维结构。 |
| 英文摘要: |
| a new compound of melamine (MA) with p-phenylenedioxydiacetic acid (p-BDOAH2), ([(MAH )2 (p-BDOA2-).4H2O]n, 1), has been prepared and its structure was characterized by X-ray crystallography. In 1, the MA molecules are protonated, the adjacent MAH cations form cationic (MAH )n chains via pairs of N-H…N hydrogen bonds, and the chains connect to each other through p-BDOA2- anions as well as lattice water molecules via extensive hydrogen bonds to form a 3D structure. |
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